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Shimizu, Kazuyuki*; Nishimura, Katsuhiko*; Matsuda, Kenji*; Akamaru, Satoshi*; Nunomura, Norio*; Namiki, Takahiro*; Tsuchiya, Taiki*; Lee, S.*; Higemoto, Wataru; Tsuru, Tomohito; et al.
Scripta Materialia, 245, p.116051_1 - 116051_6, 2024/05
Hydrogen at the mass ppm level causes hydrogen embrittlement in metallic materials, but it is extremely difficult to experimentally elucidate the hydrogen trapping sites. We have taken advantage of the fact that positive muons can act as light isotopes of hydrogen to study the trapping state of hydrogen in matter. Zero-field muon spin relaxation experiments and the density functional theory (DFT) calculations for hydrogen trapping energy are carried out for AlMn. The DFT calculations for hydrogen in AlMn have found four possible trapping sites in which the hydrogen trapping energies are 0.168 (site 1), 0.312 (site 2), 0.364 (site 3), and 0.495 (site 4) in the unit of eV/atom. Temperature variations of the deduced dipole field width () indicated step-like changes at temperatures, 94, 193, and 236 K. Considering their site densities, the observed change temperatures are interpreted by trapping muons at sites 1, 3, and 4.
Tang, J.*; Wang, Y.*; Fujihara, Hiro*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Ebihara, Kenichi; Takeuchi, Akihisa*; Uesugi, Masayuki*; Toda, Hiroyuki*
Scripta Materialia, 239, p.115804_1 - 115804_5, 2024/01
Times Cited Count:0 Percentile:0(Nanoscience & Nanotechnology)Stress corrosion cracking (SCC) behaviors induced by the combination of external and internal hydrogen (H) in an Al-Zn-Mg-Cu alloy were systematically investigated via in situ 3D characterization techniques. SCC of the Al-Zn-Mg-Cu alloy could initiate and propagate in the potential crack region where the H concentration exceeded a critical value, in which the nanoscopic H-induced decohesion of -MgZn precipitates resulted in macroscopic cracking. External H that penetrated the alloy from the environment played a crucial role during the SCC of the Al-Zn-Mg-Cu alloy by generating gradient-distributed H-affected zones near the crack tips, which made Al alloys in water environment more sensitive to SCC. Additionally, the pre-existing internal H was driven toward the crack tips during plastic deformation. It was involved in the SCC and made contributions to both the cracks initiation and propagation.
Dannoshita, Hiroyuki*; Hasegawa, Hiroshi*; Higuchi, Sho*; Matsuda, Hiroshi*; Gong, W.; Kawasaki, Takuro; Harjo, S.; Umezawa, Osamu*
Scripta Materialia, 236, p.115648_1 - 115648_5, 2023/11
Times Cited Count:0 Percentile:0(Nanoscience & Nanotechnology)Mao, W.; Gao, S.*; Gong, W.; Harjo, S.; Kawasaki, Takuro; Tsuji, Nobuhiro*
Scripta Materialia, 235, p.115642_1 - 115642_6, 2023/10
Times Cited Count:1 Percentile:0(Nanoscience & Nanotechnology)In the present study, a hybrid neutron diffraction and digital image correlation measurement was performed on tensile deformation of an ultrafine grain (UFG) stainless steel exhibiting a huge Lders band deformation to evaluate the individual contribution of the austenite matrix and the deformation-induced martensite to the strain hardening during the propagation of the band. Quantitative analysis revealed that the strain hardening of the austenite matrix was insufficient to maintain a uniform deformation when the flow stress was greatly enhanced by the UFG structure. The strain hardening required for the Lders band to propagate was mostly provided by the formation of martensite and the high internal stress within it.
Gong, W.; Kawasaki, Takuro; Zheng, R.*; Mayama, Tsuyoshi*; Sun, B.*; Aizawa, Kazuya; Harjo, S.; Tsuji, Nobuhiro*
Scripta Materialia, 225, p.115161_1 - 115161_5, 2023/03
Times Cited Count:4 Percentile:45.58(Nanoscience & Nanotechnology)Tsuchida, Noriyuki*; Ueji, Rintaro*; Gong, W.; Kawasaki, Takuro; Harjo, S.
Scripta Materialia, 222, p.115002_1 - 115002_6, 2023/01
Times Cited Count:5 Percentile:64.46(Nanoscience & Nanotechnology)Wei, D.*; Gong, W.; Kawasaki, Takuro; Harjo, S.; Kato, Hidemi*
Scripta Materialia, 216, p.114738_1 - 114738_6, 2022/07
Times Cited Count:22 Percentile:97.37(Nanoscience & Nanotechnology)Luo, M.-Y.*; Lam, T.-N.*; Wang, P.-T.*; Tsou, N.-T.*; Chang, Y.-J.*; Feng, R.*; Kawasaki, Takuro; Harjo, S.; Liaw, P. K.*; Yeh, A.-C.*; et al.
Scripta Materialia, 210, p.114459_1 - 114459_7, 2022/03
Times Cited Count:14 Percentile:91.45(Nanoscience & Nanotechnology)Shiihara, Yoshinori*; Kanazawa, Ryosuke*; Matsunaka, Daisuke*; Lobzenko, I.; Tsuru, Tomohito; Koyama, Masanori*; Mori, Hideki*
Scripta Materialia, 207, p.114268_1 - 114268_4, 2022/01
Times Cited Count:12 Percentile:73.14(Nanoscience & Nanotechnology)This study reports grain boundary (GB) energy calculations for 46 symmetric-tilt GBs in -iron using molecular mechanics based on an artificial neural network (ANN) potential and compares the results with calculations based on the density functional theory (DFT), the embedded atom method (EAM), and the modified EAM (MEAM). The results by the ANN potential are in excellent agreement with those of the DFT (5% on average), while the EAM and MEAM significantly differ from the DFT results (about 27% on average). In a uniaxial tensile calculation of GB, the ANN potential reproduced the brittle fracture tendency of the GB observed in the DFT while the EAM and MEAM mistakenly showed ductile behaviors. These results demonstrate the effectiveness of the ANN potential in calculating grain boundaries of iron, which is in high demand in modern industry.
Naeem, M.*; He, H.*; Harjo, S.; Kawasaki, Takuro; Zhang, F.*; Wang, B.*; Lan, S.*; Wu, Z.*; Wu, Y.*; Lu, Z.*; et al.
Scripta Materialia, 188, p.21 - 25, 2020/11
Times Cited Count:56 Percentile:97.51(Nanoscience & Nanotechnology)Yamashita, Takayuki; Morooka, Satoshi; Harjo, S.; Kawasaki, Takuro; Koga, Norimitsu*; Umezawa, Osamu*
Scripta Materialia, 177, p.6 - 10, 2020/03
Times Cited Count:31 Percentile:90.48(Nanoscience & Nanotechnology)Cho, K.*; Morioka, Ryota*; Harjo, S.; Kawasaki, Takuro; Yasuda, Hiroyuki*
Scripta Materialia, 177, p.106 - 111, 2020/03
Times Cited Count:35 Percentile:92.02(Nanoscience & Nanotechnology)Shoji, Eita*; Isogai, Shosei*; Suzuki, Rikuto*; Kubo, Masaki*; Tsukada, Takao*; Kai, Tetsuya; Shinohara, Takenao; Matsumoto, Yoshihiro*; Fukuyama, Hiroyuki*
Scripta Materialia, 175, p.29 - 32, 2020/01
Times Cited Count:19 Percentile:78.21(Nanoscience & Nanotechnology)Shibata, Akinobu*; Takeda, Yasunari*; Park, N.*; Zhao, L.*; Harjo, S.; Kawasaki, Takuro; Gong, W.*; Tsuji, Nobuhiro*
Scripta Materialia, 165, p.44 - 49, 2019/05
Times Cited Count:29 Percentile:85.46(Nanoscience & Nanotechnology)Bae, J. W.*; Kim, J. G.*; Park, J. M.*; Woo, W.*; Harjo, S.; Kim, H. S.*
Scripta Materialia, 165, p.60 - 63, 2019/05
Times Cited Count:24 Percentile:79.52(Nanoscience & Nanotechnology)Wang, B.*; He, H.*; Naeem, M.*; Lan, S.*; Harjo, S.; Kawasaki, Takuro; Nie, Y.*; Wang, X.-L.*; 7 of others*
Scripta Materialia, 155, p.54 - 57, 2018/10
Times Cited Count:57 Percentile:95(Nanoscience & Nanotechnology)Tomota, Yo*; Gong, W.*; Harjo, S.; Shinozaki, Tomoya*
Scripta Materialia, 133, p.79 - 82, 2017/05
Times Cited Count:24 Percentile:74.12(Nanoscience & Nanotechnology)Somekawa, Hidetoshi*; Tsuru, Tomohito
Scripta Materialia, 130, p.114 - 118, 2017/03
Times Cited Count:25 Percentile:74.12(Nanoscience & Nanotechnology)The impact of alloying elements on crack propagation and atomistic phenomenon at {102}-type twin boundaries in magnesium was investigated via both experiments and calculations. The alloying elements clearly affected crack propagation behavior. Cracks were difficult to propagate along matrix-deformation twinning interfaces in alloys that had high fracture toughness. In such magnesium alloys, the solute atoms, e.g., silver, manganese and zinc atoms, create adhesive interactions between magnesium atoms. Closed-shell and covalent-like bonding of these kinds of solute atoms would influence strong adhesion, which impedes the nucleation of a new surface at the twin boundary.
Adachi, Nozomu*; Todaka, Yoshikazu*; Suzuki, Hiroshi; Umemoto, Minoru*
Scripta Materialia, 98, p.1 - 4, 2015/03
Times Cited Count:14 Percentile:56.3(Nanoscience & Nanotechnology)The deformation texture of the high-pressure -phase of pure group IV metals was investigated using neutron diffraction analysis. The 0001 direction gradually aligned to the shear direction with an increase in the shear strain introduced by the high-pressure torsion process. The deformation texture suggested that the main slip system of the -phase was {11-20}0001. We experimentally observed the orientation relationships of the mechanically stabilized -phase with respect to the reverse-transformed -phase, and determined that the relationship was similar to that proposed by Silcock and Rabinkin.
Suzuki, Hiroshi; Saida, Junji*; Shobu, Takahisa; Katsuyama, Jinya; Kato, Hidemi*; Imafuku, Muneyuki*; Sato, Shigeo*
Scripta Materialia, 66(10), p.801 - 804, 2012/05
Times Cited Count:6 Percentile:37.98(Nanoscience & Nanotechnology)Compressive deformation mechanism of a ZrAlNiCu bulk metallic glass containing 10vol.%ZrC (ZrC-BMG) was evaluated by measuring the residual strains in the compressive deformed samples using the synchrotron X-ray diffraction and also evaluating the localized deformation behavior around the ZrC particles by the finite element analysis. Phase stress shared by the metallic glass matrix was increased before macroscopic yielding due to local plastic deformation around the ZrC particles. After macroscopic yielding, the phase stress shared by the ZrC phase was drastically increased, and finally the ZrC-BMG was fractured by breaking the ZrC particles reaching its fracture strength.